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By H. Fischer (auth.), H. Fischer (eds.)

Free radicals, that are key intermediates in lots of thermal, photochemical and radiation procedures, are very important for a formal realizing of basic common strategies and the profitable improvement of natural syntheses. VolumeII/18 serves as complement and extension to Volume II/13 and covers fee constants and different kinetic information of loose radical reactions in drinks. II/18 comprises new chapters on reactions of radicals in excited states and of carbenes, nitrenes and analogues. Species in aqueous options for which different compilations can be found have been intentionally passed over as ahead of, and for a similar cause electron move equilibria of natural radicals weren't coated. II/18E2 includes response price information on biradicals, radicals in excited states, and carbenes and similar species. Contains CD-ROM.

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Extra resources for Biradicals, Radicals in Excited States, Carbenes and Related Species

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1] nonan-9-one 27) KAS not given RT [C9H16O] O · · decay LFP (308 nm) of 2,2,6-trimethylcyclohexanone KAS methanol 300 isooctane 300 26 ) This lifetime corresponds to the excited state (fluorescent) biradical, presumed to be a triplet state. ) This work also combines KESR and CINDP studies. 1 Unimolecular biradical processes Radical’s gross formula Reaction Radical generation Method Solvent T [K] Rate data [Ref. p. / add. ref. 1] nonan-9-one 27) KAS not given RT [C9H16O] O · · decay LFP (308 nm) of 2,2,6-trimethylcyclohexanone KAS methanol 300 isooctane 300 26 ) This lifetime corresponds to the excited state (fluorescent) biradical, presumed to be a triplet state.

41 Landolt-Börnstein New Series II/18E2 Ref. p. / add. ref. 0 kG. ) This work also includes KESR and CINDP studies. 5% at both C(2) and C(12). 1 Unimolecular biradical processes Radical’s gross formula Reaction Radical generation Method Solvent T [K] [Ref. p. / add. ref. 1(3) 85Zim1 46 ) 45 ) Calculated from Fig. 1 in [85Zim1]. ) From [86Zim1]. 46 Landolt-Börnstein New Series II/18E2 Ref. p. / add. ref. 1 Unimolecular biradical processes Radical’s gross formula Reaction Radical generation Method Solvent T [K] [Ref.

Add. ref. 0 kG. ) This work also includes KESR and CINDP studies. 5% at both C(2) and C(12). 1 Unimolecular biradical processes Radical’s gross formula Reaction Radical generation Method Solvent T [K] [Ref. p. / add. ref. 1(3) 85Zim1 46 ) 45 ) Calculated from Fig. 1 in [85Zim1]. ) From [86Zim1]. 46 Landolt-Börnstein New Series II/18E2 Ref. p. / add. ref. 1 Unimolecular biradical processes Radical’s gross formula Reaction Radical generation Method Solvent T [K] [Ref. p. / add. ref. 8 T. Landolt-Börnstein New Series II/18E2 Ref.

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