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By W G Frankenburg; V I Komarewsky; Eric K Rideal


content material: entrance hide; Advances in Catalysis and comparable topics, quantity III; Copyright web page; Contents; participants to quantity III; Editors' Preface; bankruptcy 1. Balandin's Contribution to Heterogeneous Catalysis; I. advent; II. The Multiplet thought; III. dialogue of the idea; IV. Steric issues in Catalysis; References; bankruptcy 2. Magnetism and the constitution of Catalytically lively Solids; I. advent; II. normal ideas; III. Experimental equipment; IV. The Susceptibility Isotherm; V. Supported Chromium Oxide; VI. Supported Oxides of Manganese; VII. Supported Nickel Oxide VIII. Supported Iron OxideIX. Supported Copper Oxide; X. similar structures; XI. Self-Supported structures; XII. Ferromagnetism; XIII. identity of Ferromagnetic levels; XIV. response approaches; XV. answer tactics; XVI. precis; References; bankruptcy three. Catalytic Oxidation of Acetylene in Air for Oxygen Manufacture; I. creation; II. situation of Air and Acetylene; III. Acetylene removing; IV. Catalyst Compositions; V. Regeneration; VI. Mechanism of the Oxidation Reactions; VII. Mechanism of the Oxidation via Silver Nitrate; References; bankruptcy four. The Poisoning of steel Catalysts I. Catalysts at risk of PoisoningII. crucial varieties of Catalyst Poisons; III. the shape of Catalyst Poisoning Curves; IV. additional elements Influencing Toxicity; V. helpful Poisoning; References; bankruptcy five. Catalytic Cracking of natural Hydrocarbons; I. creation; II. Catalytic Cracking Reactions; III. Catalytic Cracking of Paraffins; IV. Catalytic Cracking of Olefins; V. Catalytic Cracking of Naphthenes; VI. Catalytic Cracking of fragrant Hydrocarbons; VII. constitution of Cracking Catalysts; References; bankruptcy 6. Chemical features and constitution of Cracking Catalysts I. IntroductionII. dimension of the "Acidity" of Cracking Catalysts; III. identity of the Acid facilities because the Catalytically energetic websites; IV. constitution of the Acid; V. Mechanism of Hydrocarbon Reactions on a Cracking Catalyst; References; bankruptcy 7. response premiums and Selectivity in Catalyst Pores; I. creation; III . The actual photograph of the Pore constitution; III. Mechanism of delivery in Catalyst Pores; IV. actual components picking response charges on Porous Catalysts . (Definition of cost Constants, the elemental Differential Equation and the legislation of Conservation of Mass V. response charges in unmarried PoresVI. response charges on useful Catalyst Pellets; VII. response premiums on Poisoned Catalysts (Apparent Selective Poisoning); VIII. impact of Pore constitution on Catalyst Selectivity; Appendix; thesaurus of Symbols; References; bankruptcy eight. Nickel Sulfide Catalysts; I. advent; II. The Nickel-Sulfur Equilibrium; III. actual Adsorption of Gases on Ni2S2 Catalysts; IV. Chemisorption of Gases on Ni2S2; V. helps for Stabilizing Nickel Sulfide; VI. practise of Nickel Sulfide Catalysts; VII. necessary lifestyles and Regeneration
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14. Zelinski, N. , and Balandin, A. , 2. physik. Chem. Al26, 267 (1926). 15. , Ber. 67, 1715 (1934). 16. Zelinski, N. , and Margolis, E. , Ber. 66, 1613 (1932). 17. Zelinski, N. , Ber. 44,2305 (1911). 18. Zelinski, N . , Ber. 67, 1066 (1924). 19. Lazier, W. , and Vaughen, J. , J . Am. Chem. 64, 3080 (1932). 20. Balandin, A. , and Brussow, J. , 2. physik. Chem. B34, 96 (1936). 21. Herington, E. F. , and Rideal, E. , Proc. Roy. (London) Al90, 289, 309 1. 2. 3. 4. (1947). 22. Long, J. , Frazer, J .

6. Furnace detail for Fig. 5. other the temperature. This plan is considered better than having a single line plotting magnetization and temperature only, because the magnetic properties often change with time as a component undergoes chemical reaction. A record obtained with this instrument is shown in Fig. 7. Nonrecording instruments of a somewhat different design are described elsewhere (Becker, 13). 36 P. W. SELWOOD The study of ferromagnetic substances sometimes introduces a complication that is not encountered with paramagnetic substances.

W. SELWOOD The study of ferromagnetic substances sometimes introduces a complication that is not encountered with paramagnetic substances. This is the demagnetization factor produced by the presence of any ferromagnetic substance in a field. Depending on the size, shape, and specific magnetization of the sample, the initial field in which the sample may be placed suffers reduction up to 25 per cent or more. 7. Original record of temperature and specific magnetization at saturation, obtained with recording thermomagnetic apparatus.

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